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1 article(s) from Patehebieke, Yeersen

An overview on disulfide-catalyzed and -cocatalyzed photoreactions

Yeersen Patehebieke

Beilstein J. Org. Chem. 2020, 16, 1418–1435, doi:10.3762/bjoc.16.118

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Graphical Abstract

Scheme 1: [3 + 2] cyclization catalyzed by diaryl disulfide.

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Scheme 2: [3 + 2] cycloaddition catalyzed by disulfide.

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Scheme 3: Disulfide-bridged peptide-catalyzed enantioselective cycloaddition.

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Scheme 4: Disulfide-catalyzed [3 + 2] methylenecyclopentane annulations.

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Scheme 5: Disulfide as a HAT cocatalyst in the [4 + 2] cycloaddition reaction.

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Scheme 6: Proposed mechanism of the [4 + 2] cycloaddition reaction using disulfide as a HAT cocatalyst.

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Scheme 7: Disulfide-catalyzed ring expansion of vinyl spiro epoxides.

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Scheme 8: Disulfide-catalyzed aerobic oxidation of diarylacetylene.

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Scheme 9: Disulfide-catalyzed aerobic photooxidative cleavage of olefins.

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Scheme 10: Disulfide-catalyzed aerobic oxidation of 1,3-dicarbonyl compounds.

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Scheme 11: Proposed mechanism of the disulﬁde-catalyzed aerobic oxidation of 1,3-dicarbonyl compounds.

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Scheme 12: Disulfide-catalyzed oxidation of allyl alcohols.

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Scheme 13: Disulfide-catalyzed diboration of alkynes.

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Scheme 14: Dehalogenative radical cyclization catalyzed by disulfide.

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Scheme 15: Hydrodiﬂuoroacetamidation of alkenes catalyzed by disulfide.

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Scheme 16: Plausible mechanism of the hydrodiﬂuoroacetamidation of alkenes catalyzed by disulfide.

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Scheme 17: Disulfide-cocatalyzed anti-Markovnikov olefin hydration reactions.

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Scheme 18: Disulfide-catalyzed decarboxylation of carboxylic acids.

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Scheme 19: Proposed mechanism of the disulfide-catalyzed decarboxylation of carboxylic acids.

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Scheme 20: Disulfide-catalyzed decarboxylation of carboxylic acids.

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Scheme 21: Disulfide-catalyzed conversion of maleate esters to fumarates and 5H-furanones.

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Scheme 22: Disulfide-catalyzed isomerization of difluorotriethylsilylethylene.

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Scheme 23: Disulfide-catalyzed isomerization of allyl alcohols to carbonyl compounds.

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Scheme 24: Proposed mechanism for the disulfide-catalyzed isomerization of allyl alcohols to carbonyl compound...

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Scheme 25: Diphenyl disulfide-catalyzed enantioselective synthesis of ophirin B.

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Scheme 26: Disulfide-catalyzed isomerization in the total synthesis of (+)-hitachimycin.

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Scheme 27: Disulfide-catalyzed isomerization in the synthesis of (−)-gloeosporone.

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Review

Published 23 Jun 2020

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